
Secular
Equilibrium is
a condition reached when the tphys of the
parent is many times greater than the tphys
of the daughter, e.g., 100-1000 times greater or more. For example:
1620
years 3.8 days
In
this case, the ratio of half-life of parent to half-life of the daughter is
>155,600. To keep things in perspective, during 10 half-lives of the daughter
(38 days in the example above), decay of the parent is negligible. Decay of the
parent is represented by the flat line in the diagram below.

At
the point at which activity of the parent and activity of the daughter become
equal, equilibrium has been reached and the lines become parallel (as well as
superimposed). The relationship between half-lives in secular equilibrium is
apparent
physical
t
= t
daughter
parent
This
means that in the equilibrium mixture, the daughter appears to decay with
the half-life of the parent. When the daughter is isolated from the mixture, it
has its expected half-life. Perhaps the simplest explanation for their appearing
to be equal is that the daughter can’t decay until it is formed, and so the
rate of formation of the daughter equals the rate of decay of the parent, which
is very slow. Therefore the parent and daughter appear to have the same
half-lives. In the case of the decay of Ra-226 to Rn-222, the decay constant of
the parent is 0.000001171day-1 (only 1 millionth decays per day).